Reducing trap densities of perovskite films by the addition of hypoxanthine for high-performance and stable perovskite solar cells
نویسندگان
چکیده
Perovskite solar cells (Pero-SCs) have developed rapidly in the past decade and demonstrated a power conversion efficiency (PCE) comparable to that of silicon-based quite recently; hence, they shown great potential commercialization. Solution processing perovskite films is one advantages Pero-SCs; however, uncontrollable quick crystallization through post-thermal annealing also brings voids defects between crystal grains, resulting recombination traps photoinduced excitons. To solve this problem, hypoxanthine was employed as an additive precursor assist preparation films. The quality greatly improved terms defect passivation, grain enlargement alignment. film improvement should be attributed two effects caused by hypoxanthine: 1) can slow down process thus responsible for enlarged aligned grains; 2) due nonvolatile nature, stays passivates uncoordinated Pb(II) defects. Consequently, planar n-i-p based on (FAPbI3)1-x(MAPbBr3)x presented champion PCE 22.14% maintained over 95% initial after being stored glovebox 1500 h.
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ژورنال
عنوان ژورنال: Chemical Engineering Journal
سال: 2022
ISSN: ['1873-3212', '1385-8947']
DOI: https://doi.org/10.1016/j.cej.2022.135269